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Abstract We use the H41αrecombination line to create templates of the millimeter free–free emission in the ALMA-IMF continuum maps, which allows us to separate it from dust emission. This method complements spectral-index information and extrapolation from centimeter-wavelength maps. We use the derived maps to estimate the properties of up to 34 Hiiregions across the ALMA-IMF protoclusters. The hydrogen ionizing photon rateQ₀and spectral types follow the evolutionary trend proposed by Motte et al. The youngest protoclusters lack detectable ionized gas, followed by protoclusters with increasing numbers of OB stars. The totalQ₀increases from ∼10⁴⁵s⁻¹to >10⁴⁹s⁻¹. We used the adjacent He41αline to measure the relative number abundances of helium, finding values consistent with the Galactic interstellar medium, although a few outliers are discussed. A search for sites of maser amplification of the H41αline returned negative results. We looked for possible correlations between the electron densities, emission measures, andQ₀with Hiiregion sizeD. The latter is the best correlated, withQ₀∝D^{2.49 ± 0.18}. This favors interpretations in which smaller ultracompact Hiiregions are not necessarily the less dynamically evolved versions of larger ones but rather are ionized by less massive stars. Moderate correlations were found between the dynamical width ΔV_dynwithDandQ₀. ΔV_dynincreases from about 1 to 2 times the ionized-gas sound speed. Finally, an outlier Hiiregion south of W43-MM2 is discussed. We suggest that this source could harbor an embedded stellar or disk wind.